DUAL NATURE OF MATTER

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© John Parkinson 1 WAVE WAVE PARTICLE DUALITY

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© John Parkinson 2 TOMAS YOUNG 1805 INTERFERENCE EXPERIMENT

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© John Parkinson 3 Light behaves like water waves in a ripple tank Light must be a wave max min min max max min min

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© John Parkinson 4 Light can be diffracted Light must be a wave

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© John Parkinson 5 e Photoelectric Emission! LIGHT MUST BE A PARTICLE! Photon of Light

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© John Parkinson 6 LIGHT PARTICLE OR WAVE OR WHAT?

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© John Parkinson 7 1900 PLANCK’S QUANTUM THEORY

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© John Parkinson 8 EINSTEIN (1905): Light comes in packets of energy. ENERGY OF A PHOTON is E = h f but c = f ?

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© John Parkinson 9 combining and So the effective mass of a photon is given by For yellow light with ? = 550 nm, N.B. a photon has zero rest mass

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© John Parkinson 10 THE IMAGE IN A DIGITAL CAMERA IS BUILT UP AS EACH PIXEL REACTS TO A PHOTON. The wave nature of light cannot account forindividual pixels in camera being hit.

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© John Parkinson 11 1923 : Louis de Broglie : “If a photon behaves as particle with mass, then a particle should have an associated wavelength given by i.e. the wavelength of a photon is Planck’s constant divided by its momentum, p . where v is the particle’s velocity

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© John Parkinson 12 An electron has a small mass, like a photon; might it behave as a wave ?????? Test: Can electrons be diffracted? e

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© John Parkinson 13 Wave-Particle Duality What is light? What is an electron? Are they schizophrenic? ARE THEY PARTICLES? ARE THEY WAVES? ARE THEY PARTICULATE WAVES? ARE THEY WAVY PARTICLES OR WAVICLES? It depends on the experiment you’re doing !

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© John Parkinson 14 A Moving Particle in Quantum Theory

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© John Parkinson 15 Example: de Broglie wavelength of an electron Mass = 9.11 x 10-31 kgSpeed = 1 x 106 m s-1 This wavelength is in the region of X-rays and is about the size of an atom

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© John Parkinson 16 Example: de Broglie wavelength of a ball Mass = 1 kg Speed = 1 m s-1 This is extremely small! Thus, it is very difficult to observe the wave-like behaviour of ordinary objects. Quantum Effects only becomes important at the microscopic level of atoms

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© John Parkinson 17 MATTER WAVES AN ELECTRON FIRED AT A DOUBLE SLIT the ELECTRON must travel through BOTH slits! IF WE TRY TO FIND OUT WHICH SLIT THE ELECTRON TRAVELLED THROUGH THE ELECTRON LOSES ITS WAVE NATURE, BECOMES A PARTICLE, AND PASSES THOUGH JUST ONE SLIT. Heisenburg’s Uncertainty Principle: It is impossible to determine the position and the momentum of a given particle at any particular time, as attempting to find one of these quantities will disturb the other.

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© John Parkinson 18 Given ONE electron, we cannot predict exactly where it will hit. We can only predict the PROBABILITY that it will hit a certain place on the screen: hence we can only predict the pattern that many electrons will make!! Real photographs of an electron interference pattern with increasing numbers of electrons… If we don’t look, the electron goes through both slits. If we do look it chooses one.

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© John Parkinson 19 SCREEN HOW THE PATTERN BUILDS UP Because of the Uncertainty Principle, we cannot predict where an electron is at any time. We can only talk about probability functions. Quantum Mechanics says the probability of something being in a certain place at a certain time is proportional to the square of wave function’s amplitude. When an electron passes through the double slit, its probability function splits up into two, then the two parts interfere with one another. The electrons pass through both the slits simultaneously. (Provided that no one is observing. If someone is watching, the electrons behave as particles). Protons and neutrons have been observed to behave similarly

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© John Parkinson 20 Summary Light is made up of photons, but in macroscopic situations, it is often fine to treat it as a wave. When looking at the microscopic world, there is only one thing that works… Light is made up of photons which have duality. Photons carry both energy & momentum. E = hf or E = hc / ? Matter also exhibits wave properties. For an object of mass m, and velocity, v, the object has a wavelength ? = h / mv Depending on the experiment an electron can behave like a : wave (interference and diffraction) particle (localized mass and charge)

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© John Parkinson 21 In 1935, Erwin Schrödinger proposed a "thought experiment" to highlight one of the ways in which quantum mechanics contradicts our experiences of reality. His proposal involved placing a cat (a macroscopic object) inside a closed box with a vial of cyanide and a radioactive atom initially prepared in the metastable state (a microscopic object). The radioactive atom has a probability of ½ of decaying in one hour. If it decays, then the cyanide is released and the cat dies; if it does not decay, then the cyanide is not released and the cat remains unharmed. The paradox arises because the atom, being a microscopic object, must be described by quantum mechanics. After one hour, and before it is observed, the atom is in an equal superposition of being decayed and undecayed. However, if quantum mechanics is a universal and complete theory, it must describe the whole system. And, since the state of the cat is correlated with the state of the atom, the cat must also be in a superposition of being dead and alive. If we open the box could we kill the cat? Schrödinger’s Cat