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Section 2.4—Defining, Naming & Writing Acids & Bases :Section 2.4—Defining, Naming & Writing Acids & Bases We need to know what acids behave when talking about ant-acids!
Acids :Acids
Acids – Arrhenius Definition :Acids – Arrhenius Definition Produce Hydronium ion (H3O+1) in water
Hydronium ion is water + a hydrogen cation By this definition, if an acid is to give a H+1 to water, then all acids will have hydrogen as the cation (first element written).
How do Acids produce Hydronium? :How do Acids produce Hydronium? water acid Hydrogen cation with some anion
How do Acids produce Hydronium? :How do Acids produce Hydronium? +1
How do Acids produce Hydronium? :How do Acids produce Hydronium? +1 Hydronium ion Anion
Naming Acids :Naming Acids
Naming non-oxygen Acids :These compounds have:
Start with “H” (more than 1 “H” is OK, too).
Do not contain oxygen
To name these compounds:
Use “hydro____ic acid”
Fill in the blank with the anion’s name without the last syllable Naming non-oxygen Acids
Example #1 :Example #1 HBr
Example #1 :Example #1 HBr Hydrogen cation Bromine It’s an acid No oxygen
Use “hydro___ic” Hydrobromic acid
Naming Oxygen Acids :These compounds have:
Start with “H” (more than 1 “H” is OK, too).
Do contain oxygen
To name these compounds:
Use “___ic acids” for “-ate” anions
Use “___ous acids” for “-ite” anions Naming Oxygen Acids Do not use “hydro” with these…the word “acid” is how you know it begins with hydrogen, not “hydro-”
Example #2 :Example #2 H2SO3
Example #2 :Example #2 Hydrogen cation Sulfite ion It’s an acid “-ite” ion
Use “___ous” acid H2SO3 Sulfurous acid
Example #3 :Example #3 H2SO4
Example #3 :Example #3 Hydrogen cation Sulfate ion It’s an acid “-ate” ion
Use “___ic” H2SO4 Sulfuric acid
Let’s Practice :Let’s Practice Example:
Write the name for the following compounds HCl
HNO3
H2S
H3PO3
Let’s Practice :Let’s Practice Hydrochloric acid
Nitric acid
Hydrosulfuric acid
Phosphorous acid Example:
Write the name for the following compounds HCl
HNO3
H2S
H3PO3
Writing Acid Formulas :Writing Acid Formulas
“Hydro-” acids :To write these formulas:
The cation is H+1
Write the anion and charge
Balance the charges by adding the appropriate subscript to the hydrogen cation “Hydro-” acids
Example #4 :Example #4 Hydrofluoric acid
Example #4 :Example #4 Hydrofluoric acid Hydrogen cation Does not contain oxygen H+1 F-1
Example #4 :Example #4 Hydrofluoric acid Hydrogen cation Does not contain oxygen H+1 F-1 HF H+1F-1 +1 + -1 = 0 The compound is neutral.
Subscripts are not needed
NON “Hydro-” acids :To write these formulas:
The cation is H+1
If it is an “-ic” acid, the anion is the “-ate” polyatomic ion
If it is an “-ous” acid, the anion is the “-ite” polyatomic ion
Add subscript to the hydrogen cation to balance charges NON “Hydro-” acids
Example #5 :Example #5 Carbonic acid
Example #5 :Example #5 Carbonic acid Hydrogen cation From the “___ate” anion H+1 CO3-2
Example #5 :Example #5 Carbonic acid Hydrogen cation From the “___ate” anion H+1 CO3-2 H2CO3 H+CO32- +1 + -2 = -1 H+H+CO32- +1 + 1 + -2 = 0
Example #6 :Example #6 Nitrous acid
Example #6 :Example #6 Nitrous acid Hydrogen cation From the “___ite” anion H+1 NO2-1
Example #6 :Example #6 Nitrous acid Hydrogen cation From the “___ite” anion H+1 NO2-1 HNO2 H+NO2- +1 + -1 = 0
Let’s Practice :Let’s Practice Example:
Write the formula for the following acids Phosphoric acid
Hydroiodic acid
Perchloric acid
Let’s Practice :Phosphoric acid
Hydroiodic acid
Perchloric acid Let’s Practice H3PO4
HI
HClO4 Example:
Write the formula for the following acids
Bases :Bases
Bases – Arrhenius Definition :Bases – Arrhenius Definition Bases produce the hydroxide ion in water Hydroxide Ion
Naming & Writing Bases :Naming & Writing Bases
Naming Bases :Most bases are just ionic compounds with “hydroxide” as their anion
The most common exception to this is ammonia
NH3 (ammonia) is a base even though it doesn’t contain “-OH” as the anion Naming Bases
Example #7 :Example #7 NaOH
Example #7 :Example #7 NaOH Sodium Hydroxide Sodium Hydroxide
Let’s Practice :Let’s Practice Example:
Write the formula or name for each Ca(OH)2
KOH
Sr(OH)2
Copper (II) hydroxide
Magnesium hydroxide
Let’s Practice :Let’s Practice Calcium hydroxide
Potassium hydroxide
Strontium hydroxide
Cu(OH)2
Mg(OH)2 Example:
Write the formula or name for each Ca(OH)2
KOH
Sr(OH)2
Copper (II) hydroxide
Magnesium hydroxide
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