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Atomic Theory :Atomic Theory A Short History
Leucippus (5th century BCE) :Leucippus (5th century BCE) Among the earliest originators of the idea of indivisible (un-cut-able) elements called atoms.
He also stated the Law of Causality that says everything in the world has a natural cause.
Democritus (450 BCE) :Democritus (450 BCE) Student of Leucippus
Co-originator of the belief that all matter is made up of indivisible elements called "atomos" (English word – atom)
Impossible to tell which ideas were Democritus’ and which are Leucippus’
Democritus :Democritus Basic elements exist and can be rearranged into different forms
Atoms only had several properties
size, shape, and (perhaps) weight
All other properties, such as color and taste, are the result of interactions between the atoms in our bodies and the atoms of the matter that we are examining
Democritus :Democritus The real properties of atoms determine the perceived properties of matter
Something sharp - small, pointy atoms
Something sweet - large, round atoms
Atoms of solids - hooks to attach to each other
Atoms of oils - small atoms that slip past each other
Aristotle (384 BCE – 322 BCE) :Aristotle (384 BCE – 322 BCE) student of Plato and teacher of Alexander the Great
One of the most influential of ancient Greek philosophers
Because he did not believe in a void, he reasoned that atoms could not exist
If atoms are small, discrete particles, what is between them?
Epicurus (341 BCE – 270 BCE) :Epicurus (341 BCE – 270 BCE) Founder of Epicureanism
Admitted women and slaves into his school
Believed matter was made up of uncuttable little bits of matter (atoms) flying through empty space (void)
Everything is the result of atoms interacting with one another
Lucretius (94 BCE - 49 BCE) :Lucretius (94 BCE - 49 BCE) Roman poet and philosopher
Long poem “On the Nature of Things”
He expounded the philosophy of Epicurus
Everything can be explained by motions of tiny atoms and groups of atoms interacting in empty space
Middle Ages (400’s to 1400’s) :Middle Ages (400’s to 1400’s) Civilization suffered in Western Europe
Roman knowledge became less known
Arab culture thrived – Roman texts translated into Arabic, and returned to Europe during Renaissance
Few people received schooling before 1000
Many artistic and technical skills were lost
Our current University system was created
Writers used stories and rumors as truth
Pierre Gassendi (1592 – 1655) :Pierre Gassendi (1592 – 1655) Urged the importance of experimental research
Did not accept writings blindly
Used empirical evidence to support the existance of a void
Relied on historical models to support the existance of atoms
Robert Boyle (1627 – 1691) :Robert Boyle (1627 – 1691) first modern chemist
Defined elements as we do
Invented vacuum pump
Created a vacuum and tested with sound
Gave proof that the void existed
Allows for idea of atoms
Antoine Lavosier 1743-1794 :Antoine Lavosier 1743-1794 Law of Conservation of Mass
Helps invent metric system
Dies on guillotine in French Revolution
Antoine Lavosier :Antoine Lavosier showed a compound is combusted in a closed system has no loss in mass
leads to the Law of Conservation of Mass
"mass can neither be created or destroyed in chemical reactions."
The amount started is all there at end
Joseph Proust (1754-1826) :Joseph Proust (1754-1826) formulated the Law of Definite Proportions,
"different samples of a pure chemical substance contain the same proportion of elements by mass."
Analyzed copper carbonate
Opposed by Berthole
Claude Louis Berthollet(1748 -1822) :Claude Louis Berthollet(1748 -1822) devised a chemical nomenclature
system of names
serves as the basis of the modern system of naming chemical compounds
along with Antoine Lavoisier and others
Amount of reactant effects proportions of compound
Proust vs. Berthollet :Proust vs. Berthollet Definite composition vs reactant amounts
Debated their ideas
Actual fist fight on stage once
Resolved by experimental data
Proust correct
Berthollet goes on to study equilibrium
Leads to mass-action