oxinitrideglazen

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Final presentation MDP3: Oxynitride glasses: a closer look: 

Final presentation MDP3: Oxynitride glasses: a closer look MDP 3: Sjoerd Stelwagen Peter Kalisvaart Angela van Haaren Kelly van den Hout

Structure of this presentation: 

Structure of this presentation Introduction: What is an oxynitride glass? Properties of oxynitride glass vs. oxide glass Potential applications of oxynitride glass Foamglass Hip prostheses Closure Financial report

What is an oxynitride glass?: 

What is an oxynitride glass? Network formers/modifiers N replaces O More crosslinking Changes in the properties

Changes in the properties: 

Changes in the properties Increase in: Chemical durability Resistance to subcritical crack growth Fracture toughness Young’s modulus Hardness Decrease in: Thermal expansion coefficient

Potential application (1): Foamglass: 

Potential application (1): Foamglass Introduction Present situation Possible improvements How to incorporate nitrogen? Current process (Corning) Alternatives Conclusion

Introduction: 

Introduction Foamglass Advantageous properties (good thermal insulator, non-toxic, high strength) Used in: Buildings to insulate walls, roofs and heavily loaded floors Industry to insulate pipes Foamglass

Present situation: 

Present situation Problem: Subcritical crack growth Continuous mechanical stress Chemical attack by reactive species Especially in foundations: Large stresses for very long time (decades) Chemical environment difficult to control Foamglass

Possible improvements: 

Possible improvements Important properties Resistance to subcritical crack growth Fracture toughness Chemical durability Oxynitride glass Advantages Disadvantages Foamglass

Oxynitride for foamglass (1): 

Oxynitride for foamglass (1) Advantages Increase in: Resistance to subcritical crack growth Fracture toughness Chemical durability Foamglass

Oxynitride for foamglass (2): 

Oxynitride for foamglass (2) Oxynitride glass: disadvantages Insulating capacity will most likely decrease Stresses due to thermal expansion may increase as well Foamglass

How to incorporate nitrogen? (1): 

How to incorporate nitrogen? (1) Current process (Corning) Foamglass

How to incorporate nitrogen? (2): 

How to incorporate nitrogen? (2) Alternatives Rennes: Oxide glass + AlN in oxygen atmosphere Carbothermic preparation: Oxide glass + carbon in nitrogen atmosphere Foamglass

Conclusion: 

Conclusion Oxynitride glass is an improvement because of a higher resistance to crack growth Adapting the current process should be possible, though a lot of side reactions are possible Economic benefit is yet to be evaluated. Foamglass

Potential application (2): Hip prostheses: 

Potential application (2): Hip prostheses Introduction Present situation Possible improvements Conclusion

Introduction: 

Introduction Total hip replacement rheumatoid arthritis osteoarthritis osteonecrosis seldom because of fractures Hip prostheses

Present situation (1): 

Present situation (1) Classical artificial hip: UHMWPE cup metal or ceramic ball metal femoral stem Problem: aseptic loosening Hip prostheses

Present situation (2): 

Present situation (2) First attempt to solve problem: Ceramic on ceramic (COC) couples Indication from medical world: COC bearings release too many particles which can be harmful for the human body Hip prostheses

Possible improvements (1) Overhead-sheet: 

Possible improvements (1) Overhead-sheet Hip prostheses

Possible improvements (2): 

Possible improvements (2) Mechanical properties Compressive strength Fracture toughness Young’s modulus Hardness Hip prostheses

Possible improvements (3): 

Possible improvements (3) Surface properties hydrophilicity surface roughness scratch resistance Hip prostheses

Possible improvements (4): 

Possible improvements (4) Wear properties Effect of wear particles (in-vivo) UHMWPE Ceramic Glass Hip prostheses

Conclusion: 

Conclusion Glass will most likely release less wear particles than ceramic The wear properties of oxynitride glass should be investigated further Hip prostheses

Closure: 

Closure Oxynitride glass has potential for both foamglass and hip prostheses

Financial report: 

Financial report

Word of gratitude: 

Word of gratitude We would like to thank the following persons: dr H.T. Hintzen ir D. de Graaf ir R.X.E. Willemse dr ir L.J.M.G. Dortmans dr C.C. van Donkelaar prof dr ir H.W.J. Huiskes dr K. de Smet